GHS Pictogram (According to Globally Harmonized System of Classification and Labeling of Chemicals)


Hazard
Flammable substances. Self-reactive substances pyrophoric and self-heating substances.

Precaution
Keep away from all sources of ignition. No smoking, keep container tightly.


Hazard
Oxidizing substances. Organic peroxides.

Precaution
Oxidizing substances can cause fire in contact with combustible material or promote fire once started and impede fire fighting. Do not breath vapour


Hazard
Skin corrosive. Eyes corrosive. Corrosive to metals. Causes burns.

Precaution
Contact with these substances causes destruction of living tissue as well as equipment. Do not inhale vapor. Never add water to this product.


Hazard
Sensitization (Respiratory) Mutagenicity. Carcinogenicity. Reproductive toxicity. Target organ toxicity.

Precaution
A substance which if inhaled, ingested or allowed to penetrate the skin may involve limited health risks. Possible risk of irreversible effects by immediate, prolonged or repeated exposure to these substances.


Hazard
Acute toxicity.

Precaution
All contact with the human body must be avoided as it may cause severe or lethal damage to health. A substance which if inhaled, ingested or allowed to penetrate the skin may cause serious or chronic health damage and even death. Possible risk of irreversible damage by immediate, prolonged or repeated exposure.


Hazard
Skin irritant. Eyes irritant. Sensitization (dermal).

Precaution
A substance which may have an irritating effect on skin, eyes and respiratory organs, possibility of sensitization by skin contact.


Hazard
Environmental toxicity.

Precaution
Toxic for aquatic organisms. May cause long term adverse effects in the aquatic environment. Do not allow to enter waters, waste water or soil.


Hazard
Explosives substances or articles. Self-reactive substances.

Precaution
A substance which either may explode under the effect of flame or which is more sensitive to shocks or friction than disturbance.


Hazard
Associated with compressed gase include oxygen displacemnt, fires, explosions, and toxic gas exposures as well as the physical hazards associated with high pressure system.

GHS Statements

Hazard statement codes for physical hazards
H200 : Unstable explosive
H201 : Explosive; mass explosion hazard
H202 : Explosive; severe projection hazard
H203 : Explosive; fire, blast or projection hazard
H204 : Fire or projection hazard
H205 : May mass explode in fire
H206 : Fire , blastor projection hazard; increased risk of explosion if desensitizing agent is reduced
H207 : Fire or projection hazard; increased risk of explosion if desensitizing agent is reduced
H208 : Fire hazard; increased risk of explosion if desensitizing agent is reduced
H220: Extremely flammable gas
H221: Flammable gas
H222: Extremely flammable aerosol
H223: Flammable aerosol
H224: Extremely flammable liquid and vapour
H225: Highly flammable liquid and vapour
H226: Flammable liquid and vapour
H227: Combustible liquid
H228: Flammable solid
H229: Pressurized container: may burst if heated
H230: May react explosively even in the absence of air
H231: May react explosively even in the absence of air at elevated pressure and/or temperature
H232: May ignite spontaneously if exposed to air
H240: Heating may cause an explosion
H241: Heating may cause a fire or explosion
H242: Heating may cause a fire
H250: Catches fire spontaneously if exposed to air
H251: Self-heating; may catch fire
H252: Self-heating in large quantities; may catch fire
H260: In contact with water releases flammable gases which may ignite spontaneously
H261: In contact with water releases flammable gas
H270: May cause or intensify fire; oxidizer
H271: May cause fire or explosion; strong oxidizer
H272: May intensify fire; oxidizer
H280: Contains gas under pressure; may explode if heated
H281: Contains refrigerated gas; may cause cryogenic burns or injury
H290: May be corrosive to metals

Hazard statement codes for health hazards
H300: Fatal if swallowed
H301: Toxic if swallowed
H302: Harmful if swallowed
H303: May be harmful if swallowed
H304: May be fatal if swallowed and enters airways
H305: May be harmful if swallowed and enters airways
H310: Fatal in contact with skin
H311: Toxic in contact with skin
H312: Harmful in contact with skin
H313: May be harmful in contact with skin
H314: Causes severe skin burns and eye damage
H315: Causes skin irritation
H316: Causes mild skin irritation
H317: May cause an allergic skin reaction
H318: Causes serious eye damage
H319: Causes serious eye irritation
H320: Causes eye irritation
H330: Fatal if inhaled
H331: Toxic if inhaled
H332: Harmful if inhaled
H333: May be harmful if inhaled
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335: May cause respiratory irritation
H336: May cause drowsiness or dizziness
H340: May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H341: Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H350: May cause cancer (state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard)
H351: Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard)
H360: May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is
conclusively proven that no other routes of exposure cause the hazard)
H361: Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of
exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H362: May cause harm to breast-fed children
H370: Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is
conclusively proven that no other routes of exposure cause the hazard)
H371: May cause damage to organs (or state all organs affected, if known)
(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H372: Causes damage to organs (state all organs effected,if known) through prolonged or repeated exposure
(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H373: May cause damage to organs (state all organs effected,if known) through prolonged or repeated exposure
(state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H300+H310: Fatal if swallowed or in contact with skin
H300+H330: Fatal if swallowed or if inhaled
H310+H330: Fatal in contact with skin or if inhaled
H300+H310+H330: Fatal if swallowed, in contact with skin or if inhaled
H310+H311: Toxic if swallowed or in contact with skin
H301+H331: Toxic if swallowed or if inhaled
H311+H331: Toxic in contact with skin or if inhaled
H301+H311+H331: Toxic if swallowed, in contact with skin or if inhaled
H302+H312: Harmful if swallowed or in contact with skin
H302+H332: Harmful if swallowed or if inhaled
H312+H332: Harmful in contact with skin or if inhaled
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
H303+H313: May be harmful if swallowed or in contact with skin
H303+H333: May be harmful if swallowed or if inhaled
H313+H333: May be harmful in contact with skin or if inhaled
H303+H313+H333: May be harmful if swallowed, in contact with skin or if inhaled
H315+H320: Causes skin and eye irritation

Hazard statement codes or environmental hazards
H400: Very toxic to aquatic life
H401: Toxic to aquatic life
H402: Harmful to aquatic life
H410: Very toxic to aquatic life with long lasting effects
H411: Toxic to aquatic life with long lasting effects
H412: Harmful to aquatic life with long lasting effects
H413: May cause long lasting harmful effects to aquatic life
H420: Harms public health and the environment by destroying ozone in the upper atmosphere

Codification of general precautionary statements
P101: If medical advice is needed, have product container or label at hand
P102: Keep out of reach of children
P103: Read label before use

Codification of prevention precautionary statements
P201: Obtain special instructions before use
P202: Do not handle until all safety precautions have been read and understood
P210 Keep away from heat,hot surfaces,sparks, open flames and other ignition sources. No smoking.
P211: Do not spray on an open flame or other ignition source
P212: Avoid heating under confinement or reduction of the desensitized agent
P220: Keep away from clothing and other combustible materials
P222: Do not allow contact with air
P223: Do not allow contact with water
P230: Keep wetted with Keep wetted with for substances and mixtures which are wetted, diluted, dissolved or suspended
with a plegmatizer in order to suppress their explosive properties. Manufacturer/supplier or the competent authority to specify appropriate material.
P231: Handle and store contents under inert gas. Manufacturer/supplier or the competent authority to specify appropriate
liquid or gas if I”nert gas” is not appropriate.
P232: Protect from moisture
P233: Keep container tightly closed
P234: Keep only in original packaging
P235: Keep cool
P240: Ground and bond container and receiving equipment
P241: Use explosion-proof
P242: Use non-sparking tools
P243: Take action to prevent static discharges
P244: Keep valves and fittings free from oil and grease
P250: Do not subject to grinding/shock/friction is the explosive if mechanically sensitive. Manufacturer/supplier or the competent authority
to specify applicable rough handing.
P251: Do not pierce or burn, even after use
P260: Do not breathe dust/fume/gas/mist/vapours/spray
P261: Avoid breathing dust/fume/gas/mist/vapours/spray
P262: Do not get in eyes, on skin, or on clothing
P263: Avoid contact during pregnancy and while nursing
P264: Wash … thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P271: Use only outdoors or in a well-ventilated area
P272: Contaminated work clothing should not be allowed out of the workplace
P273: Avoid release to the environment
P280: Wear protective gloves/protective clothing/eye protection/face protection
P282: Wear cold insulating gloves and either face shield or eye protection
P283: Wear fire resistant or flame retardant clothing
P284: [In case of inadequate ventilation] wear respiratory protection
P231+P232: Handle and store contents under inert gas/… Protect from moisture
Codification of response precautionary statements
P310: Immediately call a POISON CENTER/doctor. Manufacturer/supplier or the competent authority to specify the appropriate
source of emergency medical advice.
P311: Call a POISON CENTER/doctor. Manufacturer/supplier or the competent authority to specify the appropriate source
of emergency medical advice.
P312: Call a POISON CENTER/doctor/… / if you feel unwell
P313: Get medical advice/attention
P314: Get Medical advice/attention if you feel unwell
P315: Get immediate medical advice/attention
P320: Specific treatment is urgent (see … on this label)
P321: Specific treatment (see … on this label)
P330: Rinse mouth
P331: Do NOT induce vomiting
P334: Immerse in cool water[or wrap in wet bandages]
P335: Brush off loose particles from skin
P336: Thaw frosted parts with lukewarm water. Do not rub affected areas
P338: Remove contact lenses, if present and easy to do. continue rinsing
P340: Remove person to fresh air and keep comfortable for breathing
P342: If experiencing respiratory symptoms:
P351: Rinse cautiously with water for several minutes
P352: Wash with plenty of water. Manufacturer/supplier or the competent authority may specify a cleansing agent if
appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
P353: Rinse skin with water [or shower]
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P361: Take off immediately all contaminated clothing
P362: Take off contaminated clothing
P363: Wash contaminated clothing before reuse
P364: And wash it before reuse
P372: Explosion risk
P373: DO NOT fight fire when fire reaches explosives
P375: Fight fire remotely due to the risk of explosion
P376: Stop leak if safe to do so
P377: Leaking gas fire : Do not extinguish, unless leak can be stopped safely
P378: Use … to extinguish
P380: Evacuate area
P381: In case of leakage, eliminate all ignition sources
P390: Absorb spillage to prevent material – damage
P391: Collect spillage
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P301+P312: IF SWALLOWED: Call a POISON CENTER / doctor/…/if you feel unwell
P302+P334: IF ON SKIN: Immerse in cool water[or wrap in wet bandages]
P302+P352: IF ON SKIN: Wash with plenty of water. Manufacturer/supplier or the competent authority may specify a cleansing
agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate.
P304+P312: IF INHALED: Call a POISON CENTER /doctor/…/if you feel unwell
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
P306+P360: IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P308+P311: IF exposed or concerned: Call a POSION CENTER/doctor. Manufacturer/supplier or the content competent authority
to specify the appropriate source of emergency medical advice.
P308+P313: IF exposed or concerned: Get medical advice/attention
P332+P313: If skin irritation occurs: Get medical advice/attention
P333+P313: If skin irritation or a rash occurs: Get medical advice/attention
P336+P315: Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention
P337+P313: If eye irritation persists: Get medical advice/attention
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER /doctor. Manufacturer/supplier or the content competent
authority to specify the appropriate source of emergency medical advice.
P361+P364: Take off immediately all contaminated clothing and wash it before reuse
P362+P364: Take off contaminated clothing and wash it before reuse
P370+P376: In case of fire: Stop leak if safe to do so
P370+P378: In case of fire: Use … for extinguish
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302+P335+P334: IF ON SKIN: Brush if loose particles from skin. Immerse in cool water [or wrap in wet bandages]
P303+P361+P353: IF ON SKIN (or hair) : Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P370+P380+P375: In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion
P371+P380+P375: In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
P370+P372+P380+P373 : In case of fire : Explosion risk Evacuate area. DO NOT fight fire when fire reaches explosives.
P370+P380+P375 [+P378] : In case of fire : Evacuate area. Fight fire remotely due to the risk of explosion.
[Use…to extinguish]

Codification of storage precautionary statement
P401: Store in accordance with Manufacturer/supplier or the competent authority to specify local/regional/national/international regulations as applicable
P402: Store in a dry place
P403: Store in a well-ventilated place
P404: Store in a closed container
P405: Store locked up
P406: Store in a corrosive resistant/… container with a resistant inner liner
P407: Maintain air gap between stacks or pallets
P410: Protect from sunlight
P411: Store at temperatures not exceeding … ºC/… ºF
P412: Do not expose to temperatures exceeding 50ºC/122ºF
P413: Store bulk masses greater than …kg/…Ibs at temperatures not exceeding …ºC/… ºF
P420: Store separately
P402+P404: Store in a dry place. Store in a closed container
P403+P233: Store in a well-ventilated place. Keep container tightly closed
P403+P235: Store in a well-ventilated place. Keep cool
P410+P403: Protect from sunlight. Store in a well-ventilated place
P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF
Codification of disposal precautionary statements
P501 : Dispose of contents/container to in accordance with local/regional/nationnal/international regulation (to be specified).
Manufacture/suppiler or the competent authority to specify whether disposal requirements apply to contents, comtaineroe both.
P501(cont’d) : Dispose of contents/container to in accordance with local/regional/national/international regulation (to be specified).
Manufacturer/supplier or the competent authority to specify whether disposal requorement apply to contents, container or both.
P502 : Refer to manufacturer or supplier for information on recovery or recycling
European European Union Supplemental Hazard Information (EUH-Statements)
Physical properties
EUH001: Explosive when dry
EUH006: Explosive with or without contact with air
EUH014: Reacts violently with water
EUH018: In use may form flammable/explosive vapour-air mixture
EUH019: May form explosive peroxides
EUH044: Risk of explosion if heated under confinement

Health properties
EUH029: Contact with water liberates toxic gas
EUH031: Contact with acids liberates toxic gas
EUH032: Contact with acids liberates very toxic gas
EUH066: Repeated exposure may cause skin dryness or cracking
EUH070: Toxic by eye contact
EUH071: Corrosive to the respiratory tract

Environmental properties
EUH059: Hazardous to the ozone layer

Information on certain substances and mixtures
EUH201: Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH201A: Warning! Contains lead.
EUH202: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203: Contains chromium(VI). May produce an allergic reaction.
EUH204: Contains isocyanates. May produce an allergic reaction.
EUH205: Contains epoxy constituents. May produce an allergic reaction.
EUH206: Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207: Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.
Comply with the safety instructions.
EUH208: Contains <name of sensitising substance>. May produce an allergic reaction.
EUH209: Can become highly flammable in use.
EUH209A: Can become flammable in use.
EUH210: Safety data sheet available on request.
EUH401: To avoid risks to human health and the environment, comply with the instructions for use.

Sorce : United Nations , 2015

Safety Information Risk and Safety Phrases

Risk Phrases (R)
R1: Explosive when dry
R2: Risk of explosion by shock, friction, fire or other sources of ignition
R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition
R4: Forms very sensitive explosive metallic compounds
R5: Heating may cause an explosion
R6: Explosive with or without contact with air
R7: May cause fire
R8: Contact with combustible material may cause fire
R9: Explosive when mixed with combustible material
R10: Flammable
R11: Highly flammable
R12: Extremely flammable
R14: Reacts violently with water
R15: Contact with water liberates extremely flammable gases
R16: Explosive when mixed with oxidizing substances
R17: Spontaneously flammable in air
R18: In use, may form flammable/explosive vapor-air mixture
R19: May form explosive peroxides
R20: Harmful by inhalation
R21: Harmful in contact with skin
R22: Harmful if swallowed
R23: Toxic by inhalation
R24: Toxic in contact with skin
R25: Toxic if swallowed
R26: Very toxic by inhalation
R27: Very toxic in contact with skin
R28: Very toxic if swallowed
R29: Contact with water liberates toxic gas.
R30: Can become highly flammable in use
R31: Contact with acids liberates toxic gas
R32: Contact with acids liberates very toxic gas R33: Danger of cumulative effects
R34: Causes burns
R35: Causes severe burns
R36: Irritating to eyes
R37: Irritating to respiratory system
R38: Irritating to skin
R39: Danger of very serious irreversible effects
R40: Limited evidence of a carcinogenic effect
R41: Risk of serious damage to eyes
R42: May cause sensitization by inhalation
R43: May cause sensitization by skin contact
R44: Risk of explosion if heated under confinement
R45: May cause cancer
R46: May cause heritable genetic damage
R48: Danger of serious damage to health by prolonged exposure
R49: May cause cancer by inhalation
R50: Very toxic to aquatic organisms
R51: Toxic to aquatic organisms
R52: Harmful to aquatic organisms
R53: May cause long-term adverse effects in the aquatic environment
R54: Toxic to flora
R55: Toxic to fauna
R56: Toxic to soil organisms
R57: Toxic to bees
R58: May cause long-term adverse effects in the environment
R59: Dangerous for the ozone layer
R60: May impair fertility
R61: May cause harm to the unborn child
R62: Possible risk of impaired fertility
R63: Possible risk of harm to the unborn child
R64: May cause harm to breast-fed babies
R65: Harmful: may cause lung damage if swallowed
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapours may cause drowsiness and dizziness
R68: Possible risk of irreversible effects
Combination Risk Phrases (R)
R14/15: Reacts violently with water, liberating extremely flammable gases
R15/29: Contact with water liberates toxic, extremely flammable gases
R20/21: Harmful by inhalation and in contact with skin
R20/22: Harmful by inhalation and if swallowed
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
R21/22: Harmful in contact with skin and if swallowed
R23/24: Toxic by inhalation and in contact with skin
R23/25: Toxic by inhalation and if swallowed
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed
R24/25: Toxic in contact with skin and if swallowed
R26/27: Very toxic by inhalation and in contact with skin
R26/28: Very toxic by inhalation and if swallowed
R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed
R27/28: Very toxic in contact with skin and if swallowed
R36/37: Irritating to eyes and respiratory system
R36/38: Irritating to eyes and skin
R36/37/38: Irritating to eyes, respiratory system and skin
R37/38: Irritating to respiratory system and skin
R39/23: Toxic: danger of very serious irreversible effects through inhalation
R39/24: Toxic: danger of very serious irreversible effects in contact with skin
R39/25: Toxic: danger of very serious irreversible effects if swallowed
R39/23/24: Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
R39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R39/26: Very Toxic: danger of very serious irreversible effects through inhalation
R39/27: Very Toxic: danger of very serious irreversible effects in contact with skin
R39/28: Very Toxic: danger of very serious irreversible effects if swallowed
R39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
R39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/27/28: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R42/43: May cause sensitization by inhalation and skin contact
R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
R48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin
R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed
R48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
R48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation
R48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin
R48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed
R48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R68/20: Harmful: possible risk of irreversible effects through inhalation
R68/21: Harmful: possible risk of irreversible effects in contact with skin
R68/22: Harmful: possible risk of irreversible effects if swallowed
R68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin
R68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed
R68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed
R68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
Safety Phrases (S)
S1: Keep locked up
S2: Keep out of the reach of children
S3: Keep in a cool place
S4: Keep away from living quarters under… (appropriate liquid to be specified by the manufacturer)
S5: Keep contents under … (appropriate liquid to be specified by the manufacturer)
S6: Keep under … (inert gas to be specified by the manufacturer)
S7: Keep container tightly closed
S8: Keep container dry
S9: Keep container in a well-ventilated place
S12: Do not keep the container sealed
S13: Keep away from food, drink and animal feeding stuffs
S14: Keep away from … (incompatible materials to be indicated by the manufacturer)
S15: Keep away from heat
S16: Keep away from sources of ignition – No smoking
S17: Keep away from combustible material
S18: Handle and open container with care
S20: When using do not eat or drink
S21: When using do not smoke
S22: Do not breathe dust
S23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
S24: Avoid contact with skin
S25: Avoid contact with eyes
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27: Take off immediately all contaminated clothing
S28: After contact with skin, wash immediately with plenty of … (to be specified by the manufacturer)
S29: Do not empty into drains
S30: Never add water to this product
S33: Take precautionary measures against static discharges
S34: Avoid shock and friction
S35: This material and its container must be disposed of in a safe way
S36: Wear suitable protective clothing
S37: Wear suitable gloves
S38: In case of insufficient ventilation, wear suitable respiratory equipment
S39: Wear eye/face protection
S40: To clean the floor and all objects contaminated by this material use … (to be specified by the manufacturer)
S41: In case of fire and/or explosion do not breathe fumes
S42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
S43: In case of fire use … (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add – “Never use water”)
S45: In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46: If swallowed, seek medical advice immediately and show this container or label
S47: Keep at temperature not exceeding … ºC (to be specified by the manufacturer)
S48: Keep wet with … (appropriate material to be specified by the manufacturer)
S49: Keep only in the original container
S50: Do not mix with … (to be specified by the manufacturer)
S51: Use only in well-ventilated areas
S52: Not recommended for interior use on large surface areas
S53: Avoid exposure – obtain special instructions before use
S55: Treat using the best available techniques before discharge into drains or the aquatic environment
S56: Dispose of this material and its container at hazardous or special waste collection point
S57: Use appropriate container to avoid environmental contamination
S59: Refer to manufacturer/supplier for information on recovery/recycling
S60: This material and its container must be disposed of as hazardous waste
S61: Avoid release to the environment. Refer to special instructions/safety data sheet
S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
S63: In case of accident by inhalation: remove casualty to fresh air and keep at rest
S64: If swallowed, rinse mouth with water (only if the person is conscious)
Combination Safety Phrases (S)
S1/2: Keep locked up and out of the reach of children
S3/7: Keep container tightly closed in a cool place
S3/7/9: Keep container tightly closed in a cool, well-ventilated place
S3/9/14: Keep in a cool, well-ventilated place away from … (incompatible materials to be indicated by the manufacturer)
S3/9/14/49: Keep only in the original container in a cool, well-ventilated place away from … (incompatible materials to be indicated by the manufacturer)
S3/9/49: Keep only in the original container in a cool, well-ventilated place
S3/14 Keep in a cool place away from … (incompatible materials to be indicated by the manufacturer)
S7/8: Keep container tightly closed and dry
S7/9: Keep container tightly closed and in a well-ventilated place
S7/47: Keep container tightly closed and at temperature not exceeding … ºC (to be specified by the manufacturer)
S20/21: When using do not eat, drink or smoke
S24/25: Avoid contact with skin and eyes
S27/28: After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of … (to be specified by the manufacturer)
S29/35: Do not empty into drains; dispose of this material and its container in a safe way
S29/56: Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point
S36/37: Wear suitable protective clothing and gloves
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S36/39: Wear suitable protective clothing and eye/face protection
S37/39: Wear suitable gloves and eye/face protection
S47/49: Keep only in the original container at temperature not exceeding … ºC (to be specified by the manufacturer)

Hazardous Transportation and Handling Concerns
Hazardous materials are classified by the tariff system. It is important for international shipment of hazardous materials. It is shown in IMDG code (International Maritime Code for Dangerous Goods). The IMDG code has been drawn up by the IMO (International Maritime Organization of the UN). Transportation of dangerous Substances as following according to Recommendation on the Transport of Dangerous Goods, Model Regulations, Twelfth Revised edition, United Nations.

Classes


1 Explosive substances or articles


1.1 Substance and article which have a mass explosion hazard

1.2 Substances and articles which have a projection hazard but not a mass explosion hazard

1.3 Substance and article which have a re hazard and either a minor nlast hazard or a minor projection hazard or both, but not a mass explosion hazard


1.4 Substance and article which present no significant hazard


1.5 Very insensitive substances which have a mass explosion hazard


1.6 Extremely insensitive articles which do not have a mass explosion hazard

2 Gases


2.1) Flammable gases

2.2) Non-flammable, non-toxic gases


2.3) Toxic gases

3 Flammable liquids


4 Flammable solids; substances liable
to spontaneous combustion; substances which, on contact with water, emit 
ammable gases


4.1) Flamable solid

4.2) Substances liable to spontaneous combustion

4.3) Subatances which,in contact with water,emit flammable gases

5 Oxidizing substances and organic peroxides



5.1) Oxidizing substances

5.2) Organic peroxides

6 Toxic and Infectionus substances



6.1) Toxic substanecs


6.2) Infectious substances

7 Radioactive material



7A) CategoryI-White, 7B) CategoryII-Yellow, 7C) CategoryIII-Yellow


7E) Fissile material

8 Corrosive substances


9 Miscellaneous dangerous substances and articles,including environmentally hazardous substances


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